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Toxic prescribed chemicals in Sewage Effluent Discharged in the UK

AFM filtration can be applied to the filtration of waste water in order to eliminate, or at least greatly reduce the level of prescribed substances discharge into rivers and the marine environment.  We have shown that AFM can be used in combination with diffused aeration activated sludge waste water treatment of landfill leachate water to essentially prevent the discharge of toxic prescribed chemicals.  By way of example Table 1 below presents typical data for TBT ( tri-butyltin).

Table 1 TBT levels before and after AFM filtration and in the back-flush water, limit of detection 0.0038mg/l
 

Sample date

Influent mg/l

AFM effluent mg/l

AFM back-flush water mg/l

24-Jul-03

0.0046

>0.0038

0.0063

28-Jul-03

0.0038

>0.0038

0.0045

29-Jul-03

0.0038

>0.0038

0.0118

24-Dec-03

0.0052

0.004

0.0104

27-Dec-03

0.0061

>0.0038

0.0099

Table 1 shows that the AFM filter was removing TBT to below the limit of detection in all but one of the analyses. The results  demonstrate that the AFM filter is concentrating the TBT in the back-flush water and there by preventing it from being discharged to the environment.  Indeed the levels discharge by the landfill site can be up to 400 times lower than a level discharge by a sewage works located up-stream of a drinking water abstraction point.

Table 2  Environment Agency maximum permissible sewage effluent discharge levels in the UK

Substance

Discharge limit μg/l

   
Aldrin

0.02

Dieldrin

0.02

Endrin

0.01

Isodrin

0.01

Cadmium

10.0

Carbon tetrachloride

24.0

Chloroform

24.0

DDT (All isomers)

0.05

ppDDT

0.02

Hexachlorobenzene

0.06

Hexachlorobutadiene

0.2

Hexachlorohexane

0.2

Mercury

2.0

Pentachlorophenol

4.0

Trichlorobenzene

0.8

1,2-Dicloroethane

20.0

Trichloroethane

20.0

Tetrachloroethylene

20.0

Considering that the quantities of water discharge by sewage works relates to approximately 160 litres per person per day, allowing prescribed substances at the above concentration to be discharged represent a very large quantity of chemicals.  These chemicals such as TBT are bioaccumulated in the marine environment. The chemicals do not disappear but continue accumulate around the food chain increasing in concentration all of the time. The UK government guidelines now suggest that you should not eat more that two oily fish per week.  However fish meal is also used to feed cattle, chickens and other animals,  so we can not escape the problem.

We know that the population are now exposed to much high levels of chemicals than at any stage in the past.  We also know that the level of cancers in the UK have increased by around 30% over the last 30 years.  Unless some action is taken to reduce the use of chemicals and their discharge into the environment the situation can only deteriorate.

Dryden Aqua under European Commission Research project have confirmed that simple AFM tertiary treatment of sewage effluent is a cost effective means of treating waste water.  Indeed for new sewage works the adoption of AFM as opposed to humus tank sedimentation may indeed result in a lower construction costs than existing systems. The life cycle costing have also proved to be a great deal lower than any existing technology.  However the main aspect is that AFM represent effective tertiary treatment of sewage effluent, compliance with very tight discharge consents and virtual elimination of prescribed chemicals.

List 1 Prescribed substances


The Dangerous Substances Directive 76/464/EEC listed 129 so-called "black list" list 1 substances which were considered to be so toxic, persistent or bio-accumulative that efforts to control chemical releases and prevent pollution should be given the highest priority.

 

Aldrin

2-Amino-4-chlorophenol

Anthracene

Arsenic & its mineral compounds

Azinphos-ethyl

Azinphos-methyl

Benzene

Benzidene

Benzyl chloride (a -chlorotoluene)

Benzylidene chloride (a ,a -dichlorotoluene)

Biphenyl

Cadmium and its compounds

Carbon tetrachloride

Chloral hydrate

Chlordane

Chloroacetic acid

2-Chloroaniline

3-Chloroaniline

4-Chloroaniline

Chlorobenzene

1-Chloro-2,4-dinitrobenzene

2-Chloroethanol

Chloroform

4-Chloro-3-methylphenol

1-Chloronaphthalene

Chloronaphthalenes (technical mixture)

4-Chloro-2-nitroaniline

1-Chloro-2-nitrobenzene

1-Chloro-3-nitrobenzene

1-Chloro-4-nitrobenzene

4-Chloro-2-nitrotoluene

Chloronitrotoluenes (other than 4-Chloro-2-nitrotoluene)

2-Chlorophenol

3-Chlorophenol

4-Chlorophenol

Chloroprene (2-Chlorobuta-1.3-diene)

3-Chloropropene (Allyl chloride)

2-Chlorotoluene

3-Chlorotoluene

4-Chlorotoluene

2-Chloro-p-toluidine

Chlorotoluidines ( other than 2-Chloro-p-toluidine)

Coumaphos

Cyanuric chloride (2,4,6-Trichloro-1,3,5-triazine)

2,4-D (including 2,4-D-salts & 2,4-D-salts)

DDT (including metabolites DDD & DDE)

Demeton (including Demeton-o, Demeton-s, Demeton-s-methyl & Demeton-s-methylsulphone)

1,2-Dibromoethane

Dibutyltin dichloride

Dibutyltin oxide

Dibutyl tin salts (other than Dibutyltin dichloride & Dibutyltin oxide)

Dichloroanilines

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

Dichlorobenzidines

Dichlorodiisopropyl ether

1,1-Dichloroethane

1,2-Dichloroethane

1.1-Dichloroethylidene (Vinylidene chloride)

1,2-Dichloroethylene

Dichloromethane

Dichloronitrobenzenes

2,4-Dichlorophenol

1,2-Dichloropropane

1,3-Dichloropropan-2-ol

1,3-Dichloropropene

2,3-Dichloropropene

Dichlorprop

Dichlorvos

Dieldrin

Diethylamine

Disulfoton

Endosulfan

Endrin

Epichlorohydrin

Ethylbenzene

Fenitrothion

Fenthion

Heptachlor (including Heptachlorepoxide)

Hexachlorobenzene

Hexachlorobutadiene

Hexachlorocyclohexane (including all isomers and Lindane)

Hexachloroethane

Isopropylbenzene

Linuron

Malathion

MCPA

Mecoprop

Mercury & its compounds

Methamidophos

Monolinuron

Naphthalene

Omethoate

Oxydemeton-methyl

PAH (with special reference to 3,4-Benzopyrene and 3,4-Benzofluoranthene)

Parathion (including Parathion-methyl)

PCB (including PCT)

Pentachlorophenol

Phoxim

Propanil

Pyrazon

Simazine

2,4,5-T (including 2,4,5-T-salts and 2,4,5-T-esters)

1,2,4,5-Tetrachlorobenzene

1,1,2,2-Tetrachloroethane

Tetrachloroethylene

Toluene

Triazophos

Tributyl phosphate

Tributyltin oxide

Trichlorfon

Trichlorobenzene (technical mixture)

1,2,4-Trichlorobenzene

1,1,1-Trichloroethane

1,1,2-Trichloroethane

Trichloroethylene

Trichlorophenols

1,1,2-Trichlorotrifluoroethane

Trifluralin

Triphenyltin acetate (Fentin acetate

Triphenyltin chloride (Fentin chloride)

Triphenyltin hydroxide (Fentin hydroxide)

Vinyl chloride (Chloroethylene)

 

List 2

From the original list of 129 substances, Daughter Directives have been adopted providing emission limits and quality objectives for receiving water. The implementation of best available technology (BAT) is required under PPC (pollution prevention and control) authorisation for the elimination of red list  List 2 substances in discharges to water.

The black list substances covered by Daughter Directives for elevation to red list status are contained in the Environmental Protection (Prescribed Processes and Substances) Regulations 1991 (as amended). They are as follows:-

Mercury and its compounds

Cadmium and its compounds

Gamma - Hexachlorocyclohexane

DDT

Pentachlorophenol and its compounds

Hexachlorobenzene

Hexachlorobutadiene

Aldrin

Dieldrin

Endrin

PCB’s

Dichlorvos

1, 2 – Dichloroethane

Trichlorobenzene

Atrazine

Simazine

Tributyltin compounds

Triphenyltin compounds

Trifluralin

Fenitrothion

Azinphos – methyl

Malathion

Endosulfan

 

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