| DFM is a 99% pure
sulphur compressed pellet measuring approximately 4mm in diameter by 2mm.
Autotrophic bacteria such as Thiobacillus denitrificans
and Thiomicrospira denitrificans are
capable of reducing nitrate to nitrogen gas. The
energy source of autotrophic denitrifying microorganisms
is derived from oxidation-reduction reactions with
elements such as hydrogen or sulphur as the electron donor.
Autotrophic denitrifiers utilise inorganic carbon compounds (such
as CO2, HCO3-) as their carbon source. The system
therefore requires a buffer and
Magphlow Media is ideal for this application. In contrast, no
organic carbon is needed as in heterotrophic
denitrification. Another advantage of autotrophic denitrificans is
that reproduction rate is low resulting in less sludge production
which minimises the handling processes.
Autotrophic denitrification has been divided into
hydrogen-based and sulphur-based processes.
Autotrophic organisms such as Micrococcus denitrificans are
capable of reducing nitrate to nitrogen while oxidising hydrogen to
water.
55S + 50NO3- + 38H2O + 20CO2
+ 4NH+4
---->
4C5H7O2N
+ 25N2 + 55SO4-2
+ 64H+
Based on this equation, for each gram of NO 3-N
removed approximately 0.64 g cells and 2.5 g of SO42-
are generated the following buffering capacity will be
consumed.
-
5.5 grams of alkalinity as calcium carbonate (as
CaCO3) is consumed,
-
or
-
7.5 grams of alkalinity as sodium bicarbonate NaHCO3)
is consumed,
-
or
-
2.52
grams of sodium hydroxide,
-
or
-
1.89 g of MagpHlow ( magnesium oxide) media
It is therefore important to sufficient buffering in
the system, and a 50:50 ration of DFM and MagPhlow works well for the
application.
Phosphate is also consumed in the process and will
limit the rate of denitrification, so additional phosphate may be required.
This can be dosed into the water either continuously or as a batch process.
The reactions are anaerobic, so the flowrates need to be slow.
|